Quaternary Ammonium Salts Interact with Enolates and Sulfonates via Formation of Multiple +N-C-H Hydrogen Bonding Interactions

نویسندگان

چکیده

We report herein sharp physical evidence, i.e., single-crystal X-ray diffraction and 1H-NMR spectral data, confirming that quaternary ammonium species interact with anions via a set of directional ion–dipole cooperative +N-C-H unusual H-bonding interactions not pure non-directional ionic electrostatic interactions. This finding, which has been often invoked by calculations, is substantiated the preparation two model compounds an analysis their crystal structures in solid state spectra solution. These observations are particularly pertinent for rational design novel catalyses catalysts providing guidance to understanding these solution during asymmetric enantioselective catalysis.

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ژورنال

عنوان ژورنال: Catalysts

سال: 2022

ISSN: ['2073-4344']

DOI: https://doi.org/10.3390/catal12070803